Testing potential groundwater reservoir connectivity using isotopes in the south-central Karoo region
- Authors: Dlakavu, Sinazo
- Date: 2019
- Subjects: Groundwater -- South Africa -- Karoo , Hydrogeology -- South Africa Water-supply -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/39447 , vital:35248
- Description: Documenting areas with natural groundwater reservior connectivity using isotopes before the anticipated shale gas development in the Karoo Basin of South Africa could contribute to developing legislative framework for hydraulic fracturing. In this study, groundwater dynamics (primarily connectivity between old/deep and low temperature modern/shallow (<25°C) groundwater) are studied using isotopes (14C, δ18O-δ2H, 3H, and δ13C) in conjunction with geochemical parameters (sampling depth (masl) and (mbgl), temperature (°C), Electrical Conductivity (EC) (μS/m) and sustainable yield (l/s)). Previous groundwater studies conducted in the Karoo Basin suggest that 14C (pMC) has the least overlap among isotope signature constraints between the different aquifer/groundwater groups. The outcomes of 14C analysis for this study suggest that one groundwater sample is an old/deep groundwater sample (<53 pMC), and that three groundwater samples are composed of shallow/young groundwater mixed with old/deep groundwater (<74 pMC). These four relatively older samples have calculated 14C ages ≥ 1700 years and were collected from boreholes that are north-east of the Cape Mountains (~50 km). The position of these samples suggests that deep-seated faults within the Cape Mountains and the basement of the southern Karoo Basin act as preferential pathways for deep groundwater migration (as is consistent with existing deep geophysical data) to shallower depths (<60 mbgl) where it cools and/or mixes with low temperature groundwater (<25°C). Three more groundwater samples were found to match the relatively old calculated 14C ages (≥ 1700 years) of the groundwater samples collected close to the Cape Mountains even though they have modern 14C (pMC) concentrations (>74 pMC). This implies that adjusting the 14C content in Dissolved Inorganic Carbon (DIC) based on its dilution by 14C free carbonates is influential in controlling the mixed groundwater ages, and that relatively older groundwater occurs at shallow depths in other parts of the study area possibly due to linked fault systems between deep and shallow aquifers. δ18O-δ2H relationships for the sampled groundwater suggest that groundwater samples collected within the main drainage of the Great Fish River plot close to the Global Meteoric Water Line (GMWL) indicating that the recharge water to this groundwater does not experience significant evaporation. The average isotope composition of the recharging water for the all of the sampled groundwater is -7.90 ‰ and -46.72 ‰ for δ18O and δ2H, respectively. This result plots halfway between rainwater 18O-2H relationship lines for the Indian Ocean and the Atlantic Ocean. This suggests that the rainwater from which the sampled groundwater was derived from evolved from both the Indian and Atlantic Ocean waters.
- Full Text:
- Date Issued: 2019
- Authors: Dlakavu, Sinazo
- Date: 2019
- Subjects: Groundwater -- South Africa -- Karoo , Hydrogeology -- South Africa Water-supply -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/39447 , vital:35248
- Description: Documenting areas with natural groundwater reservior connectivity using isotopes before the anticipated shale gas development in the Karoo Basin of South Africa could contribute to developing legislative framework for hydraulic fracturing. In this study, groundwater dynamics (primarily connectivity between old/deep and low temperature modern/shallow (<25°C) groundwater) are studied using isotopes (14C, δ18O-δ2H, 3H, and δ13C) in conjunction with geochemical parameters (sampling depth (masl) and (mbgl), temperature (°C), Electrical Conductivity (EC) (μS/m) and sustainable yield (l/s)). Previous groundwater studies conducted in the Karoo Basin suggest that 14C (pMC) has the least overlap among isotope signature constraints between the different aquifer/groundwater groups. The outcomes of 14C analysis for this study suggest that one groundwater sample is an old/deep groundwater sample (<53 pMC), and that three groundwater samples are composed of shallow/young groundwater mixed with old/deep groundwater (<74 pMC). These four relatively older samples have calculated 14C ages ≥ 1700 years and were collected from boreholes that are north-east of the Cape Mountains (~50 km). The position of these samples suggests that deep-seated faults within the Cape Mountains and the basement of the southern Karoo Basin act as preferential pathways for deep groundwater migration (as is consistent with existing deep geophysical data) to shallower depths (<60 mbgl) where it cools and/or mixes with low temperature groundwater (<25°C). Three more groundwater samples were found to match the relatively old calculated 14C ages (≥ 1700 years) of the groundwater samples collected close to the Cape Mountains even though they have modern 14C (pMC) concentrations (>74 pMC). This implies that adjusting the 14C content in Dissolved Inorganic Carbon (DIC) based on its dilution by 14C free carbonates is influential in controlling the mixed groundwater ages, and that relatively older groundwater occurs at shallow depths in other parts of the study area possibly due to linked fault systems between deep and shallow aquifers. δ18O-δ2H relationships for the sampled groundwater suggest that groundwater samples collected within the main drainage of the Great Fish River plot close to the Global Meteoric Water Line (GMWL) indicating that the recharge water to this groundwater does not experience significant evaporation. The average isotope composition of the recharging water for the all of the sampled groundwater is -7.90 ‰ and -46.72 ‰ for δ18O and δ2H, respectively. This result plots halfway between rainwater 18O-2H relationship lines for the Indian Ocean and the Atlantic Ocean. This suggests that the rainwater from which the sampled groundwater was derived from evolved from both the Indian and Atlantic Ocean waters.
- Full Text:
- Date Issued: 2019
A study of the southwestern Karoo basin in South Africa using magnetic and gravity data
- Authors: Nxantsiya, Zusakhe
- Date: 2017
- Subjects: Groundwater -- South Africa -- Karoo
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/14043 , vital:39800
- Description: The early efforts of Booth, Johnson, Rubidge, Catuneanu, de Wit, Chevallier, Stankiewicz, Weckmann and many other scientists in studying the Karoo Supergroup has led to comprehensive documentation of the geology on the main Karoo Basin with regards to understanding the age, sedimentology, sedimentary facies and depositional environments. In spite of these studies, the subsurface structure, variations in thickness of various formations in large parts of the basin, the location and orientation of subsurface dolerite intrusions, and the depth to magnetic and gravity sources remains poorly documented. A geological study with the aid of geophysical techniques, magnetic and gravity, was conducted in the southwestern part of the main Karoo Basin. The objectives of the study were to construct numerous models of the main basin that image the crust to a depth of 45 km, to determine thicknesses of various formations, to relate observed geophysical anomalies with geological bodies and lineaments, to estimate the depth of existing anomalous bodies, to determine densities and porosity of various formations, as well as to determine the mineralogy of various rocks in the Karoo Basin. In total, seventy one rock samples were collected in the main Karoo Basin for density and mineralogical studies. The density results showed that the Beaufort and Ecca Group rocks have the low mean density of 2.490 g/cm3 amongst the rocks while the dolerite intrusions have the highest mean density of 2.697 g/cm3. The porosities of various rocks determined from the measured rock densities revealed that the Ecca Group shales, particularly the Whitehill Formation has the highest porosity of 4.5percent, while the Collingham Formation has the least porosity of 1.4 percent amongst the Ecca Group shales. Mineralogical analysis of seventeen XRD samples and 26 thin sections indicate that quartz, kaolinite, and plagioclase occur as the major mineral in most sandstones and shales in the Karoo Basin, while the pyrophyllite, smectite, and talc occur as minor minerals. Other mineral constituents include, calcite, mica, and amphibole. The 2½ dimensional (2½ D) gravity modelling along seven selected profiles, across the Beattie Magnetic Anomaly (BMA), revealed that the Ecca Group sediments, a target for shale gas exploration in the Karoo, occurs within a depth range of 0 - 4000 m from the surface. The basin deepens to a depth of 4600 m in the southwestern region, near the front of the Cape Fold Belt. It was observed as well that the Karoo dolerite sills are connected at depths and are mostly concentrated at the centre, the deepest part of the basin with some having saucer shape - like structure. These observations correspond well with the borehole data from AB 1/65 and QU 1/65 presented in Linol and de Wit (2016). Thickness isochore maps that were extracted from the gravity models indicate that the Ecca Group, which is the main target for hydrocarbon exploration, thickens to the south away from the centre of the basin and reaches thicknesses of greater than 3680 m. The Beaufort Group proves to be the thickest succession in the Karoo Basin with an estimated thickness of up to 6046 m. Constructed geophysical maps with the geology overlain reveal that most magnetic anomalies are due to dolerite intrusions, while gravity lows are due to less dense shales of the Ecca Group. The depth slices of magnetic data indicate that near surface magnetic bodies occur within the depth of 42 m from the surface whereas deep seated ones occur as deep as 9488 m and possibly deeper. Gravity depth slices reveal signatures that are predominant at depth of 2403 m are of short wavelength and are mainly lineaments and circular structures. They ultimately disappear at depth of 7120 m. The depth slices further indicate that the intensity of both magnetic and gravity long wavelength signatures become stronger with increasing depths.
- Full Text:
- Date Issued: 2017
- Authors: Nxantsiya, Zusakhe
- Date: 2017
- Subjects: Groundwater -- South Africa -- Karoo
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/14043 , vital:39800
- Description: The early efforts of Booth, Johnson, Rubidge, Catuneanu, de Wit, Chevallier, Stankiewicz, Weckmann and many other scientists in studying the Karoo Supergroup has led to comprehensive documentation of the geology on the main Karoo Basin with regards to understanding the age, sedimentology, sedimentary facies and depositional environments. In spite of these studies, the subsurface structure, variations in thickness of various formations in large parts of the basin, the location and orientation of subsurface dolerite intrusions, and the depth to magnetic and gravity sources remains poorly documented. A geological study with the aid of geophysical techniques, magnetic and gravity, was conducted in the southwestern part of the main Karoo Basin. The objectives of the study were to construct numerous models of the main basin that image the crust to a depth of 45 km, to determine thicknesses of various formations, to relate observed geophysical anomalies with geological bodies and lineaments, to estimate the depth of existing anomalous bodies, to determine densities and porosity of various formations, as well as to determine the mineralogy of various rocks in the Karoo Basin. In total, seventy one rock samples were collected in the main Karoo Basin for density and mineralogical studies. The density results showed that the Beaufort and Ecca Group rocks have the low mean density of 2.490 g/cm3 amongst the rocks while the dolerite intrusions have the highest mean density of 2.697 g/cm3. The porosities of various rocks determined from the measured rock densities revealed that the Ecca Group shales, particularly the Whitehill Formation has the highest porosity of 4.5percent, while the Collingham Formation has the least porosity of 1.4 percent amongst the Ecca Group shales. Mineralogical analysis of seventeen XRD samples and 26 thin sections indicate that quartz, kaolinite, and plagioclase occur as the major mineral in most sandstones and shales in the Karoo Basin, while the pyrophyllite, smectite, and talc occur as minor minerals. Other mineral constituents include, calcite, mica, and amphibole. The 2½ dimensional (2½ D) gravity modelling along seven selected profiles, across the Beattie Magnetic Anomaly (BMA), revealed that the Ecca Group sediments, a target for shale gas exploration in the Karoo, occurs within a depth range of 0 - 4000 m from the surface. The basin deepens to a depth of 4600 m in the southwestern region, near the front of the Cape Fold Belt. It was observed as well that the Karoo dolerite sills are connected at depths and are mostly concentrated at the centre, the deepest part of the basin with some having saucer shape - like structure. These observations correspond well with the borehole data from AB 1/65 and QU 1/65 presented in Linol and de Wit (2016). Thickness isochore maps that were extracted from the gravity models indicate that the Ecca Group, which is the main target for hydrocarbon exploration, thickens to the south away from the centre of the basin and reaches thicknesses of greater than 3680 m. The Beaufort Group proves to be the thickest succession in the Karoo Basin with an estimated thickness of up to 6046 m. Constructed geophysical maps with the geology overlain reveal that most magnetic anomalies are due to dolerite intrusions, while gravity lows are due to less dense shales of the Ecca Group. The depth slices of magnetic data indicate that near surface magnetic bodies occur within the depth of 42 m from the surface whereas deep seated ones occur as deep as 9488 m and possibly deeper. Gravity depth slices reveal signatures that are predominant at depth of 2403 m are of short wavelength and are mainly lineaments and circular structures. They ultimately disappear at depth of 7120 m. The depth slices further indicate that the intensity of both magnetic and gravity long wavelength signatures become stronger with increasing depths.
- Full Text:
- Date Issued: 2017
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