“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
- Shumba, Munyaradzi, Mashazi, Philani N, Nyokong, Tebello
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190438 , vital:44994 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyaninereduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190438 , vital:44994 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyaninereduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
- Shumba, Munyaradzi, Mashazi, Philani N, Nyokong, Tebello
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240875 , vital:50881 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240875 , vital:50881 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
'Meaningful engagement’: Towards a language rights paradigm for effective language policy implementation
- Docrat, Zakeera, Kaschula, Russell H
- Authors: Docrat, Zakeera , Kaschula, Russell H
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/174812 , vital:42512 , https://doi.org/10.1080/02572117.2015.1056455
- Description: This article aims to develop the concept of ‘meaningful engagement’ in terms of the contemporary language policy implementation framework in South Africa. By exploring the current language policies, implementation and the current lack of effectiveness, the authors offer a new implementation focus drawn from the legal concept of ‘meaningful engagement’. ‘Meaningful engagement’ is a concept within the socio-economic rights sphere. This article expands and advances the concept within a language policy framework. Against the enabling legislative environment created by the Use of Official Languages Act 12 of 2012 and the overarching Constitutional framework which embeds the rights of all official languages, ‘meaningful engagement’ is developed and applied to selected language policies and practices.
- Full Text:
- Date Issued: 2015
- Authors: Docrat, Zakeera , Kaschula, Russell H
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/174812 , vital:42512 , https://doi.org/10.1080/02572117.2015.1056455
- Description: This article aims to develop the concept of ‘meaningful engagement’ in terms of the contemporary language policy implementation framework in South Africa. By exploring the current language policies, implementation and the current lack of effectiveness, the authors offer a new implementation focus drawn from the legal concept of ‘meaningful engagement’. ‘Meaningful engagement’ is a concept within the socio-economic rights sphere. This article expands and advances the concept within a language policy framework. Against the enabling legislative environment created by the Use of Official Languages Act 12 of 2012 and the overarching Constitutional framework which embeds the rights of all official languages, ‘meaningful engagement’ is developed and applied to selected language policies and practices.
- Full Text:
- Date Issued: 2015
Utilizing gesture recognition and Ethernet AVB for distributed surround sound control
- Hedges, Mitchell, Foss, Richard
- Authors: Hedges, Mitchell , Foss, Richard
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426816 , vital:72393 , https://www.aes.org/e-lib/online/browse.cfm?elib=17540
- Description: Gesture recognition has become a preferred approach to the control of various systems. This allows users of the system to interact without having to use any controls or equipment. This paper investigates the use of gesture recognition in order to select and transport audio tracks over an Ethernet AVB network to speaker endpoints. The research uses equipment that is commercially available and relatively cost efficient. The endpoints receive audio samples that are encapsulated within network packets and processes them. The audio tracks are mixed at the endpoints according to gain ratios that will change and be different for each endpoint.
- Full Text:
- Date Issued: 2014
- Authors: Hedges, Mitchell , Foss, Richard
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426816 , vital:72393 , https://www.aes.org/e-lib/online/browse.cfm?elib=17540
- Description: Gesture recognition has become a preferred approach to the control of various systems. This allows users of the system to interact without having to use any controls or equipment. This paper investigates the use of gesture recognition in order to select and transport audio tracks over an Ethernet AVB network to speaker endpoints. The research uses equipment that is commercially available and relatively cost efficient. The endpoints receive audio samples that are encapsulated within network packets and processes them. The audio tracks are mixed at the endpoints according to gain ratios that will change and be different for each endpoint.
- Full Text:
- Date Issued: 2014
Playing broken telephone with student feedback: the possibilities and issues of transformation within a South African case of a collegial rationality model of evaluation
- Authors: Belluigi, Dina Z
- Date: 2013
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/66943 , vital:29003 , https://doi.org/10.1016/B978-1-84334-655-5.50001-5
- Description: publisher version , Drawing on the case of a small South African university which espouses a social justice approach to transformation, this chapter considers the possibilities and challenges created for student feedback within an institutional context that gives the individual lecturer a large degree of autonomy in evaluation. The chapter looks at some of the dominant perceptions of student feedback in addition to how it is collected and utilised, by referring to the institution’s policies and guideline documents; institutional research conducted with course coordinators; responses elicited from 40 lecturers on the issues outlined in this chapter; the author’s own reflections as a staff developer in the institution; and specific examples of good practice from lecturers situated within social science disciplines. The emerging concerns which structured this discussion are: the impact of student feedback on improving quality; enabling student voice; increasing student ownership; and the educational value of evaluation processes.
- Full Text: false
- Date Issued: 2013
- Authors: Belluigi, Dina Z
- Date: 2013
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/66943 , vital:29003 , https://doi.org/10.1016/B978-1-84334-655-5.50001-5
- Description: publisher version , Drawing on the case of a small South African university which espouses a social justice approach to transformation, this chapter considers the possibilities and challenges created for student feedback within an institutional context that gives the individual lecturer a large degree of autonomy in evaluation. The chapter looks at some of the dominant perceptions of student feedback in addition to how it is collected and utilised, by referring to the institution’s policies and guideline documents; institutional research conducted with course coordinators; responses elicited from 40 lecturers on the issues outlined in this chapter; the author’s own reflections as a staff developer in the institution; and specific examples of good practice from lecturers situated within social science disciplines. The emerging concerns which structured this discussion are: the impact of student feedback on improving quality; enabling student voice; increasing student ownership; and the educational value of evaluation processes.
- Full Text: false
- Date Issued: 2013
A Review of Arterial Stiffness and HIV Infection in Adult Africans
- Awotedu, Kofoworola Olajire, Iputo, Jehu
- Authors: Awotedu, Kofoworola Olajire , Iputo, Jehu
- Date: 09-06-2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/3484 , vital:43615 , https://www.hilarispublisher.com/open-access/a-review-of-arterial-stiffness-and-hiv-infection-in-adult-africans-2167-1095-1000221.pdf
- Description: Aim: To review the impact of the human immunodeficiency virus and antiretroviral therapy on the vasculature. Objectives: This review seeks to identify the burden which the human immunodeficiency virus and antiretroviral therapy have on the vasculature. Method: Medline/PubMed and Google scholar were searched. There were over 100 publications reviewed. Some people who worked in similar fields were also contacted. The present review summarized current understanding of Human immunodeficiency virus, antiretroviral therapy and effect on the vasculature such as arterial stiffness. Atherosclerosis, endothelial dysfunction, the strengths and weaknesses of current testing strategies, and their potential applications in clinical research and patient care. The association of inflammatory biomarkers, blood pressure and ageing with arterial stiffness were also reviewed. Conclusion: Available literature shows that HIV and antiretroviral agents have a great impact on the vasculature and its progression.
- Full Text:
- Date Issued: 09-06-2016
- Authors: Awotedu, Kofoworola Olajire , Iputo, Jehu
- Date: 09-06-2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/3484 , vital:43615 , https://www.hilarispublisher.com/open-access/a-review-of-arterial-stiffness-and-hiv-infection-in-adult-africans-2167-1095-1000221.pdf
- Description: Aim: To review the impact of the human immunodeficiency virus and antiretroviral therapy on the vasculature. Objectives: This review seeks to identify the burden which the human immunodeficiency virus and antiretroviral therapy have on the vasculature. Method: Medline/PubMed and Google scholar were searched. There were over 100 publications reviewed. Some people who worked in similar fields were also contacted. The present review summarized current understanding of Human immunodeficiency virus, antiretroviral therapy and effect on the vasculature such as arterial stiffness. Atherosclerosis, endothelial dysfunction, the strengths and weaknesses of current testing strategies, and their potential applications in clinical research and patient care. The association of inflammatory biomarkers, blood pressure and ageing with arterial stiffness were also reviewed. Conclusion: Available literature shows that HIV and antiretroviral agents have a great impact on the vasculature and its progression.
- Full Text:
- Date Issued: 09-06-2016
Family business: a legitimate scholarly field
- Authors: Farrington, Shelley M
- Subjects: Family-owned business enterprises , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/20934 , vital:29420
- Description: My lecture this afternoon is titled “Family business: A legitimate scholarly field”. I will first provide you with some background to family businesses and their prominence and contributions worldwide. This will be followed by an overview of how the field has evolved and where it is today. I will highlight the key role players in this evolution, some of the main challenges facing the field as well as the reasons why scholars study these businesses. I will conclude by highlighting how I believe that research on family business in South Africa can contribute to the field as a whole.
- Full Text:
- Authors: Farrington, Shelley M
- Subjects: Family-owned business enterprises , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/20934 , vital:29420
- Description: My lecture this afternoon is titled “Family business: A legitimate scholarly field”. I will first provide you with some background to family businesses and their prominence and contributions worldwide. This will be followed by an overview of how the field has evolved and where it is today. I will highlight the key role players in this evolution, some of the main challenges facing the field as well as the reasons why scholars study these businesses. I will conclude by highlighting how I believe that research on family business in South Africa can contribute to the field as a whole.
- Full Text:
Unraveling the biogeographic origins of the Eurasian watermilfoil (Myriophyllum spicatum) invasion in North America.pdf
- Identifier: http://hdl.handle.net/10962/424892 , vital:72192
- Description: Using phylogeographic analyses to determine the geographic origins of biological invaders is important for identifying environmental adaptations and genetic composition in their native range as well as biocontrol agents among indigenous herbivores. Eurasian watermilfoil (Myriophyllum spicatum) and its hybrid with northern watermilfoil (M. sibiricum) are found throughout the contiguous United States and southern Canada, forming one of the most economically costly aquatic plant invasions in North America, yet the geographic origin of the invasion remains unknown. The objectives of our study included determining the geographic origin of Eurasian watermilfoil in North America as well as the maternal lineage of the hybrids.
- Full Text:
- Date Issued: 2016
- Identifier: http://hdl.handle.net/10962/424892 , vital:72192
- Description: Using phylogeographic analyses to determine the geographic origins of biological invaders is important for identifying environmental adaptations and genetic composition in their native range as well as biocontrol agents among indigenous herbivores. Eurasian watermilfoil (Myriophyllum spicatum) and its hybrid with northern watermilfoil (M. sibiricum) are found throughout the contiguous United States and southern Canada, forming one of the most economically costly aquatic plant invasions in North America, yet the geographic origin of the invasion remains unknown. The objectives of our study included determining the geographic origin of Eurasian watermilfoil in North America as well as the maternal lineage of the hybrids.
- Full Text:
- Date Issued: 2016